diff --git a/Userland/Libraries/LibJS/Tests/builtins/Temporal/Instant/Instant.prototype.valueOf.js b/Userland/Libraries/LibJS/Tests/builtins/Temporal/Instant/Instant.prototype.valueOf.js
new file mode 100644
index 0000000000..1bffce949b
--- /dev/null
+++ b/Userland/Libraries/LibJS/Tests/builtins/Temporal/Instant/Instant.prototype.valueOf.js
@@ -0,0 +1,7 @@
+test("errors", () => {
+    test("throws TypeError", () => {
+        expect(() => {
+            new Temporal.Instant(0n).valueOf();
+        }).toThrowWithMessage(TypeError, "Cannot convert Temporal.Instant to a primitive value");
+    });
+});